Friday, May 5, 2017

INDUSTRY SPECIAL..... Methanol – energy carrier and feedstock for olefins

Methanol – energy carrier and feedstock for olefins

The global methanol market has seen significant change in recent times. New uses have emerged for the commodity chemical, even as usage in long-established ones have moderated; production is now centred in areas well endowed with competitively priced feedstock (mainly natural gas and coal); and volumes shipped across the high seas is rising as production and consumption centres have become polarised. The scale in which methanol is now produced is now unsurpassed and growth rates are surprisingly high for a large-volume commodity. China is the dominant player – both as a producer and as a consumer – and determines the fate of methanol markets globally.

Feedstock shifts to gas and coal
Methanol is produced from synthesis gas – a mixture of carbon monoxide and hydrogen – in turn produced from any hydrocarbon (oil, natural gas or coal) or even biomass. The availability of low priced natural gas, first in the Middle East, and later in pockets in Latin America, the Caribbean and North Africa, changed the fundamentals of the business, and large methanol plants came to be set up as a way of monetising the gas at a time when it had little or few alternate uses. Producers using liquid feedstock – such as naphtha – were soon edged out of the market – including several in India.
A new dimension to methanol production emerged later in China, based on a production technology that leveraged a cheap, locally available resource, coal. A rapid build-up of coal to methanol plants in the coal-producing belts in northern and north-eastern parts of the country, sharply drove up methanol capacity and production. By 2014, global methanol capacity had increased to 113-mtpa, which figure is expected to rise to a staggering 275-mtpa by 2030. By that time, China could account for about 63% of global capacity – a significant ramp-up from the 55% share now.

Variable cost positions
The cost position of methanol manufacturing is diverse, depending on the hydrocarbon feedstock used and the geographic location. Feedstock costs typically account for nearly 90% of the cash cost of producing methanol, and holds the key to competitive production. While natural gas has been the most important feedstock – historically accounting for about 85% of global installed capacity – this figure has now declined with the emergence of sizeable coal-based methanol capacity in China. In 2015, coal-based capacity accounted for about 35% of the global installed capacity and all of this was in China.
Producers in the Middle East, having access to cheap gas, are at the bottom of the cost curve for methanol, followed by producers in the North America. Production in North America has seen a remarkable resurgence thanks to the availability of cheap shale gas; nearly all methanol units had shut down by 2008 due high prices for gas. The capacity build-up now taking place will turn the region from a net importer to a net exporter even before the end of this decade.
Producers in Western Europe cracking liquids such as vacuum gas oils or naphtha are at the high end of the curve, and are increasingly meeting their requirements by imports from the Middle East and from Africa. The Chinese producers using coal as raw material come somewhere in between on the cost curve, but face the handicap of high freight costs to move methanol to coastal locations for further processing, and from tariffs imposed by importing countries.

Trade flows
Methanol trade flows have remained largely unchanged in recent years, though the quantities have grown. The major exporting regions today are South America, the Middle East and Africa, and their share of exports is expected to rise by 2030. China is set to remain a net importer of methanol, despite the build-up in capacity there; import volumes are expected to rise from about 5-mt now to about 30-mt by 2030. Nearly every exporting region will be eyeing this market!
Producers from the Middle East and Africa are well placed geographically to serve South Asian and South East Asian methanol demand and are benefitting from the low costs of shipping.

Changing demand profile
China’s impact on the methanol markets can also be gauged from the fact that it currently accounts for a little over half of global demand, which share is expected to rise to 70% by 2020. In contrast, the share of mature markets of North America and Western Europe are likely to remain more or less flat, at about 10% each.
For a large volume commodity chemical, methanol is showing high growth – faster than GDP growth – mainly due to non-conventional applications in China. This includes use as gasoline blend, and for the production of olefins through technologies commonly described as methanol-to-olefins (MTO), or more specifically as methanol-to-propylene (MTP). According to estimates made by Nexant, a consultancy, global methanol demand is expected to grow at a CAGR of about 7% between 2013 and 2030, with China the primary driver, at least in the near term.

Use as energy carrier…
The high growth comes from a fundamental transition ongong in the methanol business – from a feedstock used for making a handful of chemicals, methanol is now an energy carrier and feedstock for olefins.
The classical applications for the manufacture of formaldehyde, acetic acid and methyl tert-butyl ether (MTBE) – to name the three largest – continue to be relevant, but their growth rates are modest – at or below GDP. In contrast, methanol’s use as a direct energy carrier – as a blend into gasoline – is already the second largest single application (after use for making formaldehyde) and accounted for about 12% of global methanol demand of 71-mt in 2014. China’s use of methanol as a blend in gasoline has seen an average growth of 25% annually between 2000 and 2015!
Use for making dimethyl ether (DME) – which can be blended into diesel or used as an alternative to LPG – now accounts for about 10% of global methanol use. Again, China leads on this front. In the western economies, DME is used in a limited manner, mostly as an aerosol propellant, but in China it has penetrated markets for home heating and cooking. DME is now the fourth largest end-use for methanol globally.
To a smaller extent, methanol is also used to make fatty acid methyl esters – better known as biodiesel – from vegetable/animal fats/oils. This use accounted for about 3% of global methanol demand and is expected to rise to 4.5% by 2030 in the wake of environmental mandates to use fuels with a lower carbon footprint.

…. And as a feedstock for olefins
The demand for methanol to make olefins is unique to China, but such is the pace of investments in MTO/MTP projects that it is now globally the fastest growing application of methanol – rising 15% annually. In these units, merchant methanol – either domestically produced or imported, depending on the location of the MTO/MTP plant – is converted to much-needed olefins, by-passing availability constraints posed by lack of adequate steam cracking or refinery processing capacity. At the end of 2015 China had seven MTO units in operation, each consuming about three tonnes of methanol to make one tonne of olefins. By 2017, it is expected that methanol use for this application will surpass that for making formaldehyde – a remarkable achievement considering this end-use was unforeseen just a decade ago.

Possible uses
There is a possibility of using methanol as a bunker fuel, in the wake of the MARPOL Convention, which mandates measures for control of sulphur and nitrogen oxide emissions. The regulations require bunker operators to either use alternate fuels or build abatement systems that reduce emissions of noxious gases. While some companies have switched to methanol-fuelled vehicles, wider adoption faces hurdles including investment in new engines and competition with other clean-burning fuels such as LNG.
The use of methanol to make aromatics (benzene, toluene and xylene) is still in R&D stage, and if commercialised could open a sizeable demand outlet. With the world moving to cracking lighter feedstock, such as gas, availability of aromatics – particularly p-xylene required as a feedstock for polyester – could be a constraint. The economics will depend on methanol and coal prices (patented processes consume 4.5-tonnes of coal to produce one tonne of aromatics), but high capital costs and technical risks could stymie development. Any which way, this is not expected to be a major outlet for methanol in the near term.

Remarkable growth story
The frenetic pace of growth in methanol markets is unsustainable and will surely abate over the next few years as fuel blending plateaus to more sustainable levels in China and the rush to build MTO/MTP plants slows down given the new realities of oil based petrochemical production.
But overall demand will still see growth of about 7% annually – a remarkable number for a commodity having an installed base of more than 100-mtpa!

- Ravi Raghavan

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